<?php
$data = file_get_contents("http://www.namazvaktim.net/xml/gunluk/konya.xml");

$xml = simplexml_load_string($data) or die("Hata");

echo "İl: ".$xml->il." <br>";
echo "Gün: ".$xml->zaman->gun." <br>";
echo "İmsak: ".$xml->zaman->vakitler->imsak;