Mail olarak hazırladığın mesaja header ekleyebilirsin

.....
// To send HTML mail, the Content-type header must be set
$headers  = 'MIME-Version: 1.0' . "\r\n";
$headers .= 'Content-type: text/html; charset=iso-8859-1' . "\r\n";

$headers .= 'To: Mary <mary@example.com>, Kelly <kelly@example.com>' . "\r\n";
$headers .= 'From: Birthday Reminder <birthday@example.com>' . "\r\n";
$headers .= 'Cc: birthdayarchive@example.com' . "\r\n";
$headers .= 'Bcc: birthdaycheck@example.com' . "\r\n";

// Mail it
mail($to, $subject, $message, $headers);